曲剑萍-新利18彩票先进化学制造研究院

个人简介

2016年至今新利18彩票，先进化学制造研究院，教授

2011-2015海德堡大学化学系，博士后，洪堡学者(Günter Helmchen 教授)

2006-2011上海有机化学研究所，理学博士（唐勇研究员）

2001-2005山东师范大学化学系，理学学士

研究方向

1.新型过渡金属催化剂的设计以及在新反应开发、配位聚合反应中的应用；

2.新型功能聚合物的合成方法以及应用开发；

3.手性聚酯、聚酰胺、聚砜等光学活性聚合物的研究。

代表性论文

1. Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay, X.-H. Shan, H.-X. Zheng, B. Yang, L. Tie, Jia-Le Fu,J.-P. Qu*,Y.-B. Kang,*Nature Commun.2019,10, 908.

2. Organocatalyzed Aerobic Oxidation of Aldehydes to Acids, P.-F. Dai,J.-P. Qu*,Y.-B. Kang,*Org. Lett.DOI: 10.1021/acs.orglett.9b00101

3. Iridium-Catalyzed Asymmetric Allylic Substitution Reactions, Q. Cheng, H.-F. Tu, C. Zheng,J.-P. Qu, G. Helmchen,* Shu-Li You,*Chem. Rev.2019,119, 1855.

4. One-pot one-base conditions for two shots: organocatalyzed tandem isomerization-olefination of allylic alcohols, H.-X. Zheng, Qu,J.-P. Qu*,Y.-B. Kang,*Org. Chem. Front.2018,5, 2349.

5. Phenanthroline-tBuOK Promoted Intramolecular C–H Arylation of Indoles with ArI under Transition-Metal-Free Conditions, X.-H. Shan, B. Yang, H.-X. Zheng, Qu,J.-P. Qu*,Y.-B. Kang,*Org. Lett.2018,20,7898.

6. Strategy for Overcoming Full Reversibility of Intermolecular Radical Addition to Aldehydes: Tandem C-H and C-O Bonds Cleaving Cyclization of (Phenoxymethyl)arenes with Carbonyls to Benzofurans, H.-X. Zheng, X.-H. Shan,J.-P. Qu*,Y.-B. Kang,*Org. Lett.2018,20,3310.

7. Synthesis of Functionalized Indoles via Palladium-Catalyzed Aerobic Cycloisomerization of o-Allylanilines Using Organic Redox Cocatalyst, X.-S. Ning, M.-M. Wang, Qu,J.-P. Qu*,Y.-B. Kang,*J. Org. Chem.2018,83, 13523.

8. Tuning Regioselectivity of Wacker Oxidation in One Catalytic System: Small Change Makes Big Step, K.-F. Hu, X.-S. Ning,J.-P. Qu*,Y.-B. Kang,*J. Org. Chem.2018,83, 11327.

9. Pd-^tBuONO Cocatalyzed Aerobic Indole Synthesis, X.-S. Ning, X. Liang, K.-F. Hu, C.-Z. Yao,J.-P. Qu*,Y.-B. Kang,*Adv. Synth. Catal.2018,360, 1590.

10.ⁿBu₄NOTf-Promoted Radical Self-Hydrogen Transferring Isomerization under Transition Metal-Free Conditions H.-X. Zheng, C.-Z. Yao,J.-P. Qu*,Y.-B. Kang,*Org. Chem. Front.2018,5, 1213.

11. Synthesis of Highly Functionalized Indoles and Indolones via Selectivity-Switchable Olefinations, T.-H. Ding, Z.-F. Xiao,J.-P. Qu*,Y.-B. Kang*,J. Org. Chem.2018,83, 2467.

12. Direct Wittig Olefination of Alcohols, Q.-Q. Li, Z. Shah,J.-P. Qu*,Y.-B. Kang*,J. Org. Chem.2018,83, 296.

13. Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis,J.-P. Qu, G. Helmchen*,Acc. Chem. Res.2017,50, 2539.

14. Dehydrogenative Synthesis of Linear α,β-Unsaturated Aldehydes with Oxygen at Room Temperature Enabled by tBuONO, M.-M. Wang, X.-S. NingJ.-P. Qu*,Y.-B. Kang*,ACS Catal. 2017,7, 4000.

15. Organopromoted Selectivity-Switchable Synthesis of Polyketones, J. Liu, K.-F. Hu,J.-P. Qu*,Y.-B. Kang*,Org. Lett.2017,19, 5593.

16. H.-X. Zheng, X.-H. Shan,J.-P. Qu*, Y.-B. Kang*, Transition-Metal-Free Hydrogenation of Aryl Halides: From Alcohol to Aldehyde,Org. Lett.2017,19, 5114.

Selected Post-Doctoral and Ph.D. Publications

1. Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification, J.-P. Qu, L. Roeberg, G. Helmchen*,J. Am. Chem. Soc.2014,136, 1272.

2. Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor–Acceptor Cyclopropanes: Accessing 3a-Hydroxy [n.3.0] Carbobicycles,Xu, J.-P. Qu, S. Liao, H. Xiong, Y. Tang*,Angew. Chem. Int. Ed.2013,52, 4004.

3. Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity,J.-P. Qu, Y. Liang, H. Xu, X. Sun, Z. Yu, Y. Tang*,Chem. Eur. J.2012,18, 2196.

4. Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds,J.-P. Qu, C. Deng, J. Zhou, X. Sun, Y. Tang*,J. Org. Chem.2009,74, 7684.

5. Ligand-accelerated Asymmetric [1,2]-Stevens Rearrangment of Sufur Ylides via Decomposition of Diazomalonates Catalyzed by Chiral Bisoxazoline/Copper Complex,J.-P. Qu, Z. Xu, J. Zhou, C. Cao, X. Sun, L. Dai, Y. Tang*,Adv. Synth. Catal.2009,351, 308.

曲剑萍教授

Email:ias_jpqu@njtech.edu.cn